| 1 | Abdul-Rashid, Mariam (1997) | Speed Academy Athletics Club | 13.27 Q | +1.0 | 1v2 |
| 2 | Jacques, Farah (1990) | Perfmax-Racing | 13.38 Q | +2.2 | 1v1 |
| 3 | Nyame, Astrid (1994) | Unattached | 13.51 Q | +2.2 | 2v1 |
| 4 | Goudros, Izzy (2003) | Unattached - Ontario | 13.58 Q | +2.2 | 3v1 |
| 5 | Boug, Tyra (2000) | Speed River Track and Field Club | 13.72 Q | +1.0 | 2v2 |
| 6 | Spearchief-Morris, Joy (1994) | London Western T.F.C. | 13.86 Q | +1.0 | 3v2 |
| 7 | Whyte, Angela (1980) | APEX Athletics Club | 13.71 q | +2.2 | 4v1 |
| 8 | Léveillé, Maude (1995) | Sherbrooke | 14.00 q | +2.2 | 5v1 |
| 9 | O'Connor, Jaymie (1997) | Dynamique De Laval | 14.01 | +1.0 | 4v2 |
| 10 | Abiodun, Nike (2000) | Royal City Track & Field Club | 14.31 | +1.0 | 5v2 |
| 11 | St-Germain, Maoly (2002) | Lanaudière-Olympique | 14.88 | +1.0 | 6v2 |
| --- | Harrison, Michelle (1992) | Saskatoon Track and Field Club | DNF | +2.2 | v1 |
| --- | Moerman, Christie (1986) | Green and Gold Track and Field Club | DNS | +1.0 | v2 |