| 1 | N'doye, El-Hadj François (1989) | C.A. LaSalle | 21.92 Q | +0.0 | 1v2 |
| 2 | Muteba, Lionel Tshimanga (1990) | C.A. LaSalle | 22.15 Q | +2.7 | 1v4 |
| 3 | Généreux, Joakim (2001) | Kilomaîtres De Lasalle | 22.30 Q | +0.5 | 1v1 |
| 4 | Nelson, Jodd (1992) | Perfmax-Racing | 22.31 Q | +1.1 | 1v3 |
| 5 | Smith-Drouin, Brandon (1991) | Saint-Laurent Sélect | 22.40 Q | +1.4 | 1v5 |
| 6 | Bobak, David (1992) | C.A.N.I. Athletics | 22.39 q | +0.0 | 2v2 |
| 7 | Simoneau, Gabriel (2001) | C. A. Université Laval | 22.46 | +1.1 | 2v3 |
| 8 | Joseph, Dustie (1997) | Saint-Laurent Sélect | 22.58 (22.572) q | +1.4 | 2v5 |
| 9 | Khelifa, Azer (1997) | Saint-Laurent Sélect | 22.58 (22.577) q | +0.5 | 2v1 |
| 10 | Ahouansou, Yannis (1995) | C. A. Université Laval | 22.76 q | +1.4 | 3v5 |
| 11 | Dunning, Alexander Thunder (1998) | C.A.N.I. Athletics | 22.79 q | +0.5 | 3v1 |
| 12 | Busby, Wayne-Anthony (2000) | Saint-Laurent Sélect | 22.91 (22.902) q | +1.1 | 3v3 |
| 13 | Sixta, Nicolas (1999) | Saint-Laurent Sélect | 22.91 (22.905) q | +2.7 | 2v4 |
| 14 | Pilipili, Hento (1995) | C. A. Université Laval | 23.01 q | +1.4 | 4v5 |
| 15 | Mingot, Joan Falex (1999) | Dynamique De Laval | 23.44 q | +2.7 | 3v4 |
| 16 | Dumoulin, Chrisghary Fabrice (1998) | Dynamique De Laval | 23.68 q | +0.5 | 4v1 |
| 17 | Jiang, David (1993) | Saint-Laurent Sélect | 23.69 q | +1.1 | 4v3 |
| 18 | Dupuy, Gabriel (1994) | Perfmax-Racing | 23.71 (23.701) | +0.5 | 5v1 |
| 19 | Lebel, Henri (2000) | C. A. Université Laval | 23.71 (23.710) | +0.0 | 3v2 |
| 20 | Baptiste, Hacheming (1993) | Indépendant | 23.75 | +1.4 | 5v5 |
| 21 | Bérubé, Antoine (1995) | Saint-Laurent Sélect | 23.76 | +2.7 | 4v4 |
| 22 | Krejcik, Peter (1997) | Saint-Laurent Sélect | 23.85 | +0.0 | 4v2 |
| 23 | Chouinard-Laliberte, Simon (1995) | Saint-Laurent Sélect | 23.88 | +0.0 | 5v2 |
| 24 | Damphousse, Luc (2001) | Enduromax | 23.93 | +0.5 | 6v1 |
| 25 | McGhie, Kadeem (1997) | Indépendant | 23.97 | +2.7 | 5v4 |
| 26 | Menezes Thibault, Olivier (2000) | Tarus | 24.02 | +2.7 | 6v4 |
| 27 | Bouliane-Longchamps, Samuel (2001) | Zénix De La Mauricie | 24.12 | +1.4 | 6v5 |
| 28 | Ceant, Jordy Cruff Fredlenz (2000) | Sherbrooke | 24.20 | +1.4 | 7v5 |
| 29 | Grondin-Bernier, Samuel (1996) | Corsaire-Chaparral | 24.32 (24.317) | +0.5 | 7v1 |
| 30 | Lamoureux, Damien (1993) | Gatineau | 24.32 (24.319) | +0.5 | 8v1 |
| 31 | Rajendram, Juthishan (2003) | Saint-Laurent Sélect | 24.37 | +1.4 | 8v5 |
| 32 | Chartier, Thomas (2001) | Zénix De La Mauricie | 24.43 | +1.1 | 5v3 |
| 33 | Romdhani, Malik (2002) | Dynamique De Laval | 24.44 | +2.7 | 7v4 |
| 34 | Narloch, Théo Juca (1997) | Saint-Laurent Sélect | 25.21 | +1.1 | 6v3 |
| 35 | Légaré, Jean-Pierre (1994) | Vainqueurs Plus | 25.45 | +1.1 | 7v3 |
| 36 | Bouchard, Frédéric (2004) | Mustangs | 26.27 | +1.1 | 8v3 |
| 37 | Salazar, Mauricio (1969) | Lanaudière-Olympique | 28.38 | +2.7 | 8v4 |
| 38 | Cordeiro Beaupré, Alexi (2001) | Rive-Sud | 33.27 | +0.0 | 6v2 |
| --- | LeBlanc, Émile (1998) | Sherbrooke | DNS | +0.0 | v2 |
| --- | Macdowell, Evan (2002) | Vaudreuil-Dorion | DNS | +0.0 | v2 |